First, Welcome to B&B!
If I understand the question correctly, you're asking if it's ok to use an aftershave of one scent and deodorant/antiperspirant of a different scent. I do that every day, to no ill effect. If you're asking whether you can use AS in concert with and as part of the daily deodorizing process, I don't know, I've never tried.
Is it acceptable to mix deodorants with after shaves?
Thanks,
I'm getting colognes mixed up with aftershave.
I just don't want all the scents clashing with my cologne, and sometimes find it hard to indicate if it is.