Oh yea, absolutely. In fact I usually shave at night so I can take my time and unwind from the day doing something that relaxes me. Plus it gives me more time to work out in the morning. After my morning shower, I splash on a little more aftershave before off to work. I don't even use cologne.
I apply Ogallala Bay Rum, Lime & Peppercorns every morning, regardless of whether or not I've shaved. I like the scent and I like the witch hazel's effect
If I ever use some kind of aftershave without shaving, it is always a little bit of Nivea Sensitive balm (or lotion if it is a good day to be outside and riding the motorbike since it has an SPF of 4 or something) followed by some Clubman; it just makes me feel, I don't know, scruffy yet sophisticated, which I think the ladies like these days.