Frank Shaving can make a 30mm knot, but dont make handles that big right now, and its an ok knot. There are many 35mm synthetic kabuki's that are great for shaving.
GDCarrington, I'm not sure I'v seen that compacting in my bigger synthetics. Have you used some that do?
H.I.S. at 28mm x 60mm is one of the largest synthetic knots. Few, if any, manufacturers will go past that because the fibers compact too much and would make a brush that is difficult to use.
By custom are you speaking of the knot itself, or a synthetic knot in a custom handle?