Interesting thread!
I've been going with a routine advocated in a 50's vintage science article on shaving. To summarize:
Hot water wash with soap.
Rinse
Repeat the hot water wash, rinse OR leave the soap on face if it's not irritating.
Lather up.
Wait two minutes for the lather to do it's thing
Shave away.
Any of you fifty pound Razorbrain chemical whangdoodlers see big holes in this?
If I read some of the post above sorta correctly, the Alky-lides in the soap are breaking the H-bonds, and the hot water might be flushing out them pesky and crunchy Saltine bonds, too.
The Steering Acids and other magic stuff in my Lather needs time to work on my now De-Bonded beard, so the two minutes I let it set while I brush my fangs lets the Lather blot inside my facial hairs, changing the Steering acid to Blotter acid.
Shaving then cuts off the now De-Bonded, acid softened, heated and hydrated hairs by moving a really sharp thing through them whiskers.
Is that right?
what he said!